返回届次CSCP-ICC-2024-295

Study on electrochemical properties of titanium-oxide Ru0.3LaxTi(0.7-x) electrode*

作者

Chunlian LuoJianhua WuYanling Yang

单位

2.Key Laboratory for Marine Corrosion and Intelligent Protection Materials of Xiamen、Jimei University、Xiamen 361000、China 3.Navigation College、Xiamen Ocean Vocation College、Xiamen 361000、China

关键词

AC impedanceMetal oxide electrodeChlorine anodeMechanismAccelerated life

收录来源

International Corrosion Congress · 第22届国际腐蚀大会

摘要

The Ru0.3LaxTi(0.7-x) electrodes are made by sol -gel method. The effect on chlorine evolution performance, st rengthening life and surface morphology of electrodes doped with La 2O3 are studied. Results: The titanium etched by acid and then alkali has a large specific surface area, while the titanium etched by acid had no obvious nanopore; The incorporation of La 2O3 could reduce the film resistance and electrochemical transfer resistance of the electrode, enhance the conductivity of the coating; The electrode doped with 1% La 2O3 coating has a smaller electrochemical transfer resistance than Commercial DSA under the same unit molar mass of Ru, which will reduce the cost of Ru; The electrode doped with 1% La2O3 has the highest reaction rate constant among the electrode doped with 0%La 2O3, 2%La2O3 and 3% La2O3; The electrode doped with 1% La 2O3 has higher life than the electrode doped with 2% La2O3 and 3% La2O3.

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