返回届次CSCP-ICC-2024-724

The corrosion behavior and passive film properties of the cast and annealed AlCoCrFeNi2.1 eutectic high-entropy alloy in sulfuric acid solution

作者

Yu Fu123Hong LuoXinren ChenManoj PrabhakarXuefei WangHongxu ChengCuiwei Du1Songqing HuXiaogang Li

单位

1Beijing Advanced Innovation Center for Materials Genome Engineering、University of Science and Technology Beijing、100083 Beijing、China 2Max Planck Institute for Sustainable Materials、Max-Planck-Str. 1、40237 Dü sseldorf、Germany 3School of Materials Science and Engineering、China University of Petroleum (East China)、266580 Qingdao、China

关键词

High-entropy alloyCorrosion behaviorPassive filmAESXPS

收录来源

International Corrosion Congress · 第22届国际腐蚀大会

摘要

The effect of microstructure on the corrosion behavior and film properties of strengthened AlCoCrFeNi 2.1 eutectic high -entropy a lloy (EHEA) was investigated. Annealing of the 80% cold -rolled AlCoCrFeNi 2.1 EHEA at 650 -1200 °C effectively improved the stable passive region to 930 mV, and decreased the passive current density by 25% to 3.5 μA/cm 2 compared with the cast alloy in 0.1 M H 2SO4 solution. The improved corrosion resistance of the annealed AlCoCrFeNi 2.1 EHEA was attributed to the increasing oxides proportion and thickness of passive film and the reduced composition difference between FCC and B2 phases. The B2 phase in lamellae suffered the severest corrosion.

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