Modeling Hydrogen embrittlement of Ti6Al4V fabricated by laser beam powder bed

摘要

Hydrogen embrittlement (HE) behavior of Ti6Al4V produced by laser beam powder bed fusion (PBF -LB) was investigated via tensile tests with/without electrochemical H-charging, and the heat treatment (HT, 950 °C for 2 h) effects on HE mechanisms were also explored. Decreased resistance against HE after long-term H-charging is verified for the HT PBF-LB Ti6Al4V and this phenomenon is not obvious for the as-built (AS) PBF-LB counterparts. To understand this observation, we carried out microstructural characterization experiments including backscattered electron (BSE) image, electron backscatter diffraction (EBSD), transmission electron microscope (TEM), and hydrogen analyses based on X -ray diffraction (XRD) and the rmal desorption spectrometry (TDS). These results and others reveal that the β phase introduced by the HT process attracts more hydrogen ingress compared with the full acicular α ́ martensitic phase in the AS PBF -LB parts. The lattice expansion of the hydrogenated β phase compels a localized stress field n ear the phase boundary, leading to an increased workhardening rate under H -charging for the HT PBF -LB Ti6Al4V. Consequently, brittle titanium hydrides occur along with the α/β interfaces after H-charging, and the micro -voids preferentially initiate therein and coalesce to micro - cracks under plastic deformation. Therefore, a larger ductility loss is verified for the HT PBF-LB Ti 6Al4V compared with the AS PBF -LB counterparts under the same H - charging condition.